Cannot send mail from Windows 8 Mail app

Installed Win8 pro (upgrade to win7 x 64) a few days before and set up the Mail app to work with all my email accounts. I have several: a gmail, an outlook.com and three or four regular POP3/IMAP on mine, hosted domains. The problem is I can't send e-mails from any IMAP accounts or the account of outlook.com. I receive emails OK but sending does not work - they end just the Outbox and then nothing happens.

This doesn't seem to be a problem of parameters - I use the same settings as in my Outlook 2010 client and I chatted with hosting support (they confirmed my settings, each of them). However, I noticed that when manually "sync" I got error messages saying temporary get accounts are 'not available' (top right). This is true for my POP3/IMAP accounts as well as the outlook.com account. May be a temporary problem, however, since I have no problem receiving e-mails.
I used a downloadable apps Win8 mechanic I found here at Microsoft Answers, but he found nothing. And nobody else seems to have this problem (neither here, nor on other forums). What could be wrong?
Any suggestions on how to deal with this issue would be greatly appreciated. I was hoping to invest in a Windows Phone 8 later, but I would like to first of all of course e-mail work.

Please wait for the update to be available in different markets. The 16.4.4406.1205 version is the most recent with the fix.

Added October 17, 2013

8.1 Windows upgrade, Mail App will support invalid server certificates (not match error with CN, untrusted root and expiry of the certificate). This means that the user can temporarily reject the certificate error when connecting to the IMAP/EAS server using the SSL connection. The setting is available jet account-> Settings.

Tags: Windows

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