How to stop search engines view my pdf files?

My client has a high priority control that displays the details of the product and asked that a form is completed before anyone can access a page where there is a spec sheet pdf,.

It was all fine and dandy until that one of the pdf files has appeared high on a Google search.

How can I prevent the search engines to find and list of these files?

Page field, the properties of metadata:

Tags: Adobe Muse

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